张雯宇, 高昇, 张晨光, 贾芯芮, 李欢, 岳宣志, 武多多, 范耀春, 秦钰涵. 2021年内蒙古自治区城市生活饮用水8种化学物健康风险评价[J]. 环境与职业医学, 2023, 40(11): 1283-1289. DOI: 10.11836/JEOM23123
引用本文: 张雯宇, 高昇, 张晨光, 贾芯芮, 李欢, 岳宣志, 武多多, 范耀春, 秦钰涵. 2021年内蒙古自治区城市生活饮用水8种化学物健康风险评价[J]. 环境与职业医学, 2023, 40(11): 1283-1289. DOI: 10.11836/JEOM23123
ZHANG Wenyu, GAO Sheng, ZHANG Chenguang, JIA Xinrui, LI Huan, YUE Xuanzhi, WU Duoduo, FAN Yaochun, QIN Yuhan. Health risk assessment of eight chemicals in urban drinking water in Inner Mongolia Autonomous Region in 2021[J]. Journal of Environmental and Occupational Medicine, 2023, 40(11): 1283-1289. DOI: 10.11836/JEOM23123
Citation: ZHANG Wenyu, GAO Sheng, ZHANG Chenguang, JIA Xinrui, LI Huan, YUE Xuanzhi, WU Duoduo, FAN Yaochun, QIN Yuhan. Health risk assessment of eight chemicals in urban drinking water in Inner Mongolia Autonomous Region in 2021[J]. Journal of Environmental and Occupational Medicine, 2023, 40(11): 1283-1289. DOI: 10.11836/JEOM23123

2021年内蒙古自治区城市生活饮用水8种化学物健康风险评价

Health risk assessment of eight chemicals in urban drinking water in Inner Mongolia Autonomous Region in 2021

  • 摘要: 背景

    生活饮用水安全与人群健康息息相关。近年来相关研究发现内蒙古自治区生活饮用水仍存在一些问题,内蒙古自治区地幅辽阔,复杂多样的自然环境可能使得各地饮用水质量不一。

    目的

    对2021年内蒙古自治区城市饮用水中砷、镉、铬(六价)、铅、汞、氟化物、三氯甲烷和四氯化碳8种化学物进行评估,为优化城市供水系统提供数据参考,为进一步制定促进人群健康策略提供思路。

    方法

    在内蒙古各地区城区共设置监测点1228个,于枯水期(5月)和丰水期(8~9月)各进行1次水样采集,并按照《生活饮用水标准检验方法》检测饮用水中8种化学物,应用美国环境保护署(USEPA)推荐的健康风险评价模型,参照《化学物质环境健康风险评估技术指南》进行化学物质环境健康风险评估。采用Mann-Whitney U检验比较不同水期、不同水样类型城市饮用水中8种化学物的浓度。

    结果

    2021年内蒙古自治区城市饮用水共检测2381份城市饮用水水样,其中丰水期水样1195份,枯水期水样1186份;出厂水水样389份,末梢水水样1992份。砷元素和氟化物的检出率较高,分别为26.25%、96.77%,镉、铬(六价)、铅、汞、三氯甲烷和四氯化碳的检出率分别6.22%、16.63%、6.09%、16.67%、18.98%和8.36%。氟化物超标率较高,为4.87%,三氯甲烷和四氯化碳未发现超标。砷、镉、铬(六价)、铅、四氯化碳在不同水期城市饮用水中的含量均存在统计学差异(Z=−3.847,P<0.05;Z=2.464,P=0.014;Z=−3.129,P=0.002;Z=4.341,P<0.05;Z=4.342,P<0.05)。8种化学物中仅氟化物的浓度在不同水样类型中存在统计学差异(Z=−2.287,P=0.022)。不同水期、不同水样类型饮用水中各化学物经口和经皮摄入的非致癌风险小于1,但经口摄入非致癌总风险的P95大于1。经口摄入致癌风险的P95显示不同水期、不同水样类型饮用水中的部分化学物存在一定的致癌风险,致癌风险大于10−4,化学物经皮摄入的致癌风险均小于10−6

    结论

    2021年内蒙古自治区城市饮用水总体情况较好,但砷、镉、铬(六价)、铅、汞、氟化物仍有超标情况,存在一定健康风险。

     

    Abstract: Background

    The safety of drinking water is closely related to people's health. In recent years, relevant studies have identified some health related problems with drinking water in Inner Mongolia Autonomous Region. The complex and diverse natural environment embraced by the vast jurisdiction of the region may lead to uneven drinking water quality across the region.

    Objective

    To evaluate eight chemicals including arsenic, cadmium, chromium (hexavalent), lead, mercury, fluoride, trichloromethane, and carbon tetrachloride in urban drinking water in Inner Mongolia Autonomous Region in 2021, and to provide reference for optimizing urban water supply system and ideas for further developing strategies to promote population health.

    Methods

    A total of 1228 monitoring sites were set up in urban areas of Inner Mongolia, and water samples were collected once in dry season (May) and once in wet season (August−September). Eight chemicals of interest in drinking water were detected according to the Standard examination methods for drinking water, and assessed for health risks using the health risk assessment model recommended by the United States Environmental Protection Agency (USEPA) and following the Technical guide for environmental health risk assessment of chemical exposure. Mann-Whitney U test was used to compare the concentrations of eight chemicals in urban drinking water by water seasons and water sample types.

    Results

    In 2021, a total of 2381 samples of urban drinking water were tested in the Inner Mongolia Autonomous Region, including 1195 samples in wet season and 1186 samples in dry season; 389 samples of finished water and 1992 samples of tap water. The positive rates of arsenic and fluoride were 26.25% and 96.77%, respectively. The positive rates of cadmium, chromium (hexavalent), lead, mercury, trichloromethane, and carbon tetrachloride were 6.22%, 16.63%, 6.09%, 16.67%, 18.98%, and 8.36%, respectively. The exceeding standard rate of fluoride was 4.87%. Trichloromethane and carbon tetrachloride were qualified in all samples. There were statistical differences in the concentrations of arsenic, cadmium, chromium (hexavalent), lead, and carbon tetrachloride in urban drinking water between water seasons (Z=−3.847, P<0.05; Z=2.464, P=0.014; Z=−3.129, P=0.002; Z=4.341, P<0.05; Z=4.342, P<0.05). Only fluoride concentration was found statistically different among different water sample types (Z=−2.287, P=0.022). The non-carcinogenic risks of ingestion and dermal exposure to each chemical in drinking water by water seasons and water sample types were all less than 1, but the P95 total non-carcinogenic risks of oral exposure were greater than 1. The P95 carcinogenic risks of oral exposure to some chemicals in drinking water by water seasons and water sample types were>10−4, which suggested carcinogenic risks, while the carcinogenic risks of dermal explore to chemicals were all less than 10−6.

    Conclusion

    In 2021, urban drinking water in Inner Mongolia Autonomous Region is generally safe, but arsenic, cadmium, chromium (hexavalent), lead, mercury, and fluoride still exceed the national limits, posing certain health risks.

     

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