2017—2021年河北省城区生活饮用水中化学物的检测及慢性非致癌风险评估

Detection and chronic non-carcinogenic risk assessment of chemicals in urban drinking water in Hebei Province from 2017 to 2021

  • 摘要:
    背景 河北省坐落于华北平原,鉴于地质背景的影响及饮用水毒理学指标超标对人体的急慢性危害,加之城区供水覆盖规模较大,并且自建设施供水仍然存在,掌握城市地区的饮用水卫生状况并进行健康风险评价很有必要。
    目的 探讨影响河北省城区生活饮用水水质达标率的主要指标,并评估11种化学物指标的慢性非致癌风险。
    方法 按照GB/T 5750—2006《生活饮用水卫生标准检验方法》对2017—2021年河北省城区出厂水、末梢水和二次供水进行采集、保存和检测,共收集14299份饮用水样本。根据GB 5749—2006《生活饮用水卫生标准》对11种化学物达标情况进行评价。采用美国国家环境保护署“四步法”健康风险评估模型和WS/T 777—2021《化学物质环境健康风险评估技术指南》,对饮用水中11种化学物经口途径暴露导致的慢性非致癌风险进行评估。
    结果 2017—2021年河北省城区饮用水中砷、镉、六价铬、铅、汞、硒、氰化物、三氯甲烷和四氯化碳指标达标率均为100.00%,氟化物和硝酸盐(以N计)为影响水质达标的主要指标,达标率分别为97.68%和99.53%。氟化物指标达标率呈逐年上升趋势(χ2=178.06,P<0.05),浓度呈下降趋势(χ2=563.49,P<0.05);丰水期水样氟化物达标率高于枯水期(χ2=5.06,P<0.05)。2017—2021年河北省城区饮用水中5年氟化物和硝酸盐浓度的中位数为0.36和3.32 mg·L−1,风险值分别为0.15和0.05,均小于1,认为不会对健康造成慢性非致癌损害,男女性别差异不明显。氟化物浓度最大值的风险值为1.65,大于1,可能会对健康造成慢性非致癌损害。其余10项化学指标的浓度最大值的慢性非致癌风险均在可接受范围。
    结论 2017—2021年河北省城区饮用水中除氟化物和硝酸盐之外的9项化学指标未见超标。氟化物和硝酸盐为影响水质总体达标率的主要毒理学指标,硝酸盐最大暴露浓度和氟化物95%暴露浓度的慢性非致癌风险处于可接受水平。

     

    Abstract:
    Background Hebei Province is located in the North China Plain. In view of the influence of geological background and the acute and chronic hazards caused by excessive drinking water toxicological indicators, coupled with the large coverage of water supply in urban areas and the existence of self-built water supply facilities, it is necessary to understand the drinking water sanitation status in urban areas and conduct health risk assessment.
    Objective To investigate main indicators affecting the compliance rate of drinking water quality in urban areas of Hebei and evaluate the chronic non-carcinogenic risks of 11 chemicals.
    Methods The collection, preservation, and testing of 14299 samples of finished water, tap water, and secondary water supply in urban areas of Hebei Province from 2017 to 2021 were conducted following the Standard examination methods for drinking water (GB/T 5750—2006). A total of 11 chemicals were evaluated according to the Hygienic standards for drinking water (GB 5749—2006). The chronic non-carcinogenic risks of the 11 chemicals in drinking water by oral exposure were assessed using the four-step health risk assessment model developed by the United States Environmental Protection Agency and the Technical guide for environmental health risk assessment of chemical substances (WS/T 777—2021).
    Results From 2017 to 2021, the compliance rates of arsenic, cadmium, hexavalent chromium, lead, mercury, selenium, cyanide, chloroform, and carbon tetrachloride in drinking water in urban areas of Hebei Province were all 100.00%, and fluoride and nitrate (N) were the main indicators affecting water quality compliance, with compliance rates of 97.68% and 99.53% respectively. The compliance rate of fluoride increased year by year (χ2=178.06, P<0.05), and the concentration showed a downward trend (χ2=563.49, P<0.05). The compliance rate of fluoride in water samples during the wet season was higher than that during the dry season (χ2=5.06, P<0.05). The median concentrations of fluoride and nitrate in drinking water in urban areas of Hebei Province from 2017 to 2021 were 0.36 mg·L−1 and 3.32 mg·L−1, with hazard quotients of 0.15 and 0.05, respectively, both less than 1, suggesting no chronic non-carcinogenic risks, and no significant gender difference was found. The hazard quotient of maximum fluoride concentration was 1.65, which was greater than 1, suggesting chronic non-carcinogenic risks. The chronic non-carcinogenic risks associated with the maximum concentrations of the remaining 10 chemical indicators were all within an acceptable range.
    Conclusions  Nine toxicological indicators in drinking water in urban areas of Hebei Province from 2017 to 2021, except for fluoride and nitrate, are within the national standards. Fluoride and nitrate are the main toxicological indicators that affect the overall compliance rate of water quality, and the chronic non-carcinogenic risks associated with maximum concertration of nitrate and 95% concentration of fluoride are at an acceptable level.

     

/

返回文章
返回